This adds a degree of tension to the relationship, and as long as you make sure the antagonist is less of a "villain", we're allowed to root for them.
As the name indicates, this tends to be the gender dynamic of a male hero and a female villain.
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Gag Dana with your cock and she’ll love you forever.
And once her little butthole is loosened up for you to slide your big fat cock right there, she’ll bend right over her desk and watch you work your magic.
The one-sided version of this may be a Villainous Crush.